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| (000000-000000- - 5033) |
Date of Issue:
12/7/2005 12:00:00 AM |
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Supercedes:
1/5/2005 12:00:00 AM |
Chemical Name &
Synonyms:
N/A |
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Trade Name &
Synonyms:
X-433
AEROSOL |
Chemical Family:
PETROLEUM MIXTURE
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Formula is a
mixture: [√] |
Manufacturer Name:
CERTIFIED LABS, DIV. OF NCH
CORP. |
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Manufacturer
Address:
BOX 152170
IRVING, TEXAS 75015
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Prepared By:
L Boynton/Chemist |
Product Code Number:
5033 |
Emergency Phone
Number:
800-424-9300 | |
| THE HAZARDS PRESENTED BELOW ARE THOSE OF THE
INDIVIDUAL COMPONENTS |
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| (NON-HAZARDOUS INGREDIENT NAMES AND
CAS NUMBERS ARE PROTECTED UNDER NJ TRADE) |
| Secret Registry #: 409363 - 5078P |
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| Boiling Point (°F): |
500°
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Specific Gravity
(H20=1): |
0.9
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| Vapor Pressure (mm Hg): |
2024
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Color: |
BLACK |
| Vapor Density (Air=1): |
1.7
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Odor: |
PETROLEUM
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| pH @ 100% : |
N/A |
Clarity: |
OPAQUE
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| % Volatile by Volume: |
22
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Evaporation Rate (BuAc=1): |
24.6
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| H20 Solubility: |
NEGLIGIBLE
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Viscosity: |
NON-VISCOUS
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| Flash Point: |
>200°F |
Method Used: |
SETAFLASH
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| Flammable Limits: |
HEX GLYCOL/PROPANE
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UEL: |
9.5%
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| LEL: |
1.2%
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Aerosol Level (NFPA
30B): |
3 | |
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| Special Fire Fighting
Procedures: FIREFIGHTERS SHOULD
WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
GEAR. EXTINGUISHING MEDIA SHOULD BE CHOSEN BASED ON THE NATURE
OF THE SURROUNDING FIRE. COOL FIRE-EXPOSED CONTAINERS WITH
WATER SPRAY TO PREVENT BURSTING. |
| Unusual Fire and Explosion
Hazards: THE USE OF WATER
SPRAY (F0G) WHILE EFFECTIVE, MAY CAUSE FROTHING AND FOAMING.
NEVER USE A WATER JET AS THIS WILL JUST SPREAD THE FIRE.
PRODUCT MAY PRODUCE A FLOATING FIRE HAZARD AS LIQUID FLOATS ON
WATER. FLAME EXTENSION: 10 INCHES, BURNBACK: 0 INCHES.
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Threshold
Limit Value:
NOT ESTABLISHED FOR
MIXTURE. SEE SECTION II. |
| Effects
of Overexposure: |
Acute: (Short Term
Exposure)
EYE CONTACT: CAUSES
SEVERE IRRITATION SEEN AS TEARING, SWELLING, STINGING,
REDNESS, EXCESSIVE BLINKING, A BURNING SENSATION, AND BLURRED
VISION. MAY CAUSE CORNEAL DAMAGE. SKIN CONTACT: MAY CAUSE
ALLERGIC SKIN REACTION SEEN AS DELAYED SKIN RASH WHICH MAY BE
FOLLOWED BY BLISTERING, SCALING, AND OTHER SKIN EFFECTS. MAY
CAUSE IRRITATION SEEN AS BLISTERING, ITCHING, REDNESS,
SWELLING, AND A BURNING SENSATION. PROLONGED OR REPEATED
CONTACT AS FROM CLOTHING WET WITH MATERIAL MAY CAUSE DRYING,
DEFATTING, AND CRACKING OF THE SKIN. INHALATION: MAY CAUSE
CHEST PAIN AND RESPIRATORY IRRITATION SEEN AS COUGHING,
SNEEZING, AND NASAL DISCHARGE. AT LOW VAPOR CONCENTRATIONS, NO
HARMFUL EFFECTS ARE EXPECTED. AT HIGH VAPOR CONCENTRATIONS,
INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS
HEADACHE, DIZZINESS, DROWSINESS, WEAKNESS, UNCONCIOUSNESS,
POSSIBLE ANESTHETIC EFFECTS FROM CENTRAL NERVOUS SYSTEM
DEPRESSION, AND MAY BE FATAL. INGESTION: MAY CAUSE IRRITATION
WITH POSSIBLE NAUSEA, VOMITING, AND DIARRHEA. MAY CAUSE
CENTRAL NERVOUS SYSTEM EFFECTS SIMILAR TO INHALATION.
INGESTION AND SUBSEQUENT VOMITING OF THIS PRODUCT CAN LEAD TO
ASPIRATION OF THE PRODUCT INTO THE LUNGS WHICH CAN CAUSE
DAMAGE AND MAY BE FATAL. |
Chronic: (Long Term
Exposure)
MAY CAUSE SKIN
SENSITIZATION IS SOME INDIVIDUALS. ON RARE OCCASIONS,
PROLONGED AND REPEATED EXPOSURE TO OIL MIST POSES A RISK OF
CHRONIC LUNG INFLAMMATION. THIS CONDITION IS USUALLY
ASYMPTOMATIC AS A RESULT OF REPEATED SMALL ASPIRATIONS.
SHORTNESS OF BREATH AND COUGHING ARE THE MOST COMMON SYMPTOMS.
ASPIRATION MAY LEAD TO PULMONARY EDEMA AND HEMORRHAGE AND MAY
BE FATAL. SIGNS OF LUNG INVOLVEMENT INCLUDE INCREASED
RESPIRATION AND HEART RATES AS WELL AS A BLUISH DISCOLORATION
OF THE SKIN. CHRONIC SKIN CONTACT MAY PROMOTE DERMATITIS AND
OIL ACNE. IN RARER CASES, AN INCREASED SENSITIVITY TO SUNLIGHT
(PHOTOSENSITIVITY) MAY OCCUR. MEDICAL CONDITIONS AGGRAVATED BY
EXPOSURE ARE PRE-EXISTING RESPIRATORY AND SKIN CONDITIONS SUCH
AS ASTHMA, EMPHYSEMA, AND DERMATITIS. TARGET ORGANS: LUNGS,
LIVER, KIDNEYS, BLADDER, AND CENTRAL NERVOUS
SYSTEM. |
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| Emergency
First Aid Procedures: |
Inhalation:
REMOVE FROM THE
AREA TO FRESH AIR. SEEK MEDICAL ATTENTION IF RESPIRATORY
IRRITATION DEVELOPS OR IF BREATHING BECOMES
DIFFICULT. |
Eye Contact:
IMMEDIATELY RINSE
THE EYES WITH WATER. REMOVE ANY CONTACT LENSES AND CONTINUE
FLUSHING FOR AT LEAST 15 MINUTES. HOLD THE EYELIDS APART TO
ENSURE RINSING OF THE ENTIRE SURFACE OF THE EYES AND LIDS WITH
WATER. GET IMMEDIATE MEDICAL ATTENTION. |
Skin Contact:
WIPE AWAY MATERIAL
WITH A CLOTH WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
WASH WITH SOAP AND WATER. SEEK MEDICAL ATTENTION IF IRRITATION
DEVELOPS. CLEAN CLOTHING AND SHOES. |
Ingestion:
GIVE 3 TO 4 GLASSES
OF WATER, BUT DO NOT INDUCE VOMITING. IF VOMITING OCCURS, GIVE
FLUIDS AGAIN. GET IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING
PERSON. |
Notes to Physician:
INGESTION AND
SUBSEQUENT VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF
THE PRODUCT INTO THE LUNGS WHICH CAN CAUSE DAMAGE AND MAY BE
FATAL. DEPENDING ON THE AMOUNT INGESTED AND RETAINED AS WELL
AS THE TOXICITY OF THE PRODUCT, GASTRIC LAVAGE SHOULD BE
CONSIDERED. KEEP PATIENT'S HEAD BELOW HIPS TO PREVENT
PULMONARY ASPIRATION. IF COMATOSE, A CUFFED ENDOTRACHAEL TUBE
WILL PREVENT
ASPIRATION. | |
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VOC CONTENT: 15.6%
BY WEIGHT; 21.8% BY VOLUME; 131.1
G/L
PETROLATUM
SKN-RBT TDLO: 100 ML/KG/30D-I
4.
SODIUM SULFONATE
ORL-RAT LD50: >5 G/KG
3.
SKN-RAT LD50: >2 G/KG 3.
HEXYLENE
GLYCOL
ORL-RAT LD50: 3700 MG/KG 4.
ORL-RAT LDL0: 33600
MG/KG/28D-I CHANGES IN LIVER, BLADDER, KIDNEY 4.
IHL-RAT
LC50: NO DEATHS: 66 PPM/8H 3.
SKN-RBT LD50: 8560 UL/KG
4.
SKN-RBT SDT: 465 MG/24H 4.
EYE-RBT SDT: 93 MG/24H
SEVERE 4.
IN A REPEATED PATCH TEST STUDY OF ECZEMA
PATIENTS, HEXYLENE GLYCOL ELICITED EDEMA AND ERYTHEMA IN 2.8%
OF THE SUBJECTS TESTED (CONTACT DERMATITIS 21:154, 1989)
3.
HEXYLENE GLYCOL HAS PRODUCED EVIDENCE OF SLIGHT
FETAL TOXICITY AT A MATERNALLY TOXIC DOSE (1000 MG/KG/DAY)
3.
MINERAL SPIRITS
IHL-RAT LC: >5500 MG/M3/4H
4.
ORL-RAT LD50: >5 G/KG 4.
SKN-RBT LD50: >3 G/KG
4.
EYE-RBT SDT: 500 MG/24H MODERATE 4.
LIGHT
NAPHTHENIC HYDROTREATED PTEROLEUM DISTILLATE
ORL-RAT LD50:
>5 GM/KG 4.
SKN-RBT LD50: >2 GM/KG 4.
SKN-RBT SDT:
500 MG SEVERE 4.
HEAVY NAPHTHENIC SEVERELY HYDROTREATED
PETROLEUM DISTILLATE
ORL-RAT LD50: >5 G/KG 3.
SKN-RBT LD50: >3 G/KG 3.
SKN-RBT IRRITATION
<0.5/8.0; NO APPRECIABLE EFFECT 3.
EYE-RBT IRRITATION
<15/110; NO APPRECIABLE EFFECT 3.
MINERAL OIL AND
HYDROCARBON MISTS DERIVED FROM HIGHLY REFINED OILS AND
PETROLEUM DISTILLATES ARE REPORTED TO HAVE LOW ACUTE AND
SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS WELL
ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG
INFLAMMATORY REACTION, LIPOID GRANULOMA FORMATION, AND LIPOID
PNEUMONIA. IN ACUTE AND SUB-ACUTE STUDIES INVOLVING EXPOSURES
TO LOWER CONCENTRATIONS AT OR NEAR CURRENT WORK PLACE EXPOSURE
LEVELS PRODUCED NO SIGNIFICANT TOXICOLOGICAL EFFECTS. IN LONG
TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC EFFECTS HAVE
BEEN REPORTED IN ANY ANIMAL SPECIES TESTED. THESE PETROLEUM
DISTILLATES ARE SEVERELY HYDROTREATED, SEVERELY SOLVENT
EXTRACTED, AND/OR PROCESSED BY MILD HYDROTREATMENT AND
EXTRACTION. FOR THIS REASON, THEY ARE NOT CLASSIFIED AS CANCER
HAZARDS. 3.
PROPANE
IHL-LC50 >40% BY VOLUME
3.
N-BUTANE
IHL-RAT LC50: 658 G/M3/4H
4.
HUMAN VOLUNTEERS EXPOSED REPEATEDLY TO GASES OF
SIMILAR HYDROCARON MIXTURES RANGING FROM 250 TO 1000 PPM
EXHIBITED NO CARDIAC OR PULMONARY FUNCTION ABNORMALITIES.
3.
POLYBUTENE COPOLYMER
ORL-RAT LD50: >34600
MG/KG 3.
SKN-RAT LD50: >10250 MG/KG 3.
SKN-RBT:
1.5/8.0, SLIGHT IRRITANT 3.
EYE-RBT: <8.0/110, COMPLETE
DISAPPEARANCE OF EFFECTS WITHIN 72 HOURS 3.
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Incompatibility (Materials to
Avoid):
STRONG OXIDIZING
AGENTS SUCH AS CHLORINE BLEACH AND CONCENTRATED HYDROGEN
PEROXIDE, DICHROMATES, AND PERMANGANATES; STRONG ACIDS,
ALDEHYDES, KETONES, ACID CLAYS. |
Hazardous Decomposition
Products:
OXIDES OF CARBON,
NITROGEN, SODIUM, AND SULFUR; ALDEHYDES AND
KETONES. | |
Steps to be Taken if Material is
Released or Spilled:
DUE TO THE NATURE
OF THE AEROSOL PACKAGING, A LARGE SPILL IS UNLIKELY. FOR A
SMALL SPILL, WEAR APPROPRIATE PROTECTIVE CLOTHING, VENTILATE
THE AREA, ABSORB WITH AN INERT MATERIAL, AND TRANSFER ALL
MATERIAL INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. USE
CARE AS SPILLS MAY BE SLIPPERY. |
Waste Disposal
Method(s):
DISPOSE OF IN
ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS.
TYPICAL DISPOSAL IS TO WRAP THE EMPTY AEROSOL CONTAINER IN
SEVERAL LAYERS OF NEWSPAPER AND DISPOSE OF IN THE TRASH.
AEROSOL RECYCLING PROGRAMS ARE AVAILABLE IN MANY AREAS. DO NOT
PUNCTURE OR INCINERATE THIS CONTAINER. |
Neutralizing Agent:
N/A | |
Required
Ventilation:
LOCAL VENTILATION
IS RECOMMENDED TO CONTROL EXPOSURE FROM OPERATIONS THAT CAN
GENERATE EXCESSIVE LEVELS OF VAPORS OR MISTS. LOCAL
VENTILATION IS PREFERRED, BECAUSE IT PREVENTS DISPERSION INTO
WORK AREAS BY CONTROLLING IT AT ITS SOURCE. |
Respiratory
Protection:
RESPIRATORS SHOULD
BE SELECTED BY AND USED UNDER THE DIRECTION OF A TRAINED
HEALTH AND SAFETY PROFESSIONAL FOLLOWING REQUIREMENTS FOUND IN
OSHA'S RESPIRATOR STANDARD (29 CFR 1910.134) AND ANSI'S
STANDARD FOR RESPIRATORY PROTECTION (Z88.2-1992). FOR
CONCENTRATIONS ABOVE THE TLV AND/OR PEL BUT LESS THAN 10 TIMES
THESE LIMITS, A NIOSH APPROVED HALF-FACEPIECE RESPIRATOR
EQUIPPED WITH APPROPRIATE CHEMICAL CARTRIDGES MAY BE USED. FOR
CONCENTRATIONS GREATER THAN 10 TIMES THE TLV AND/OR PEL,
CONSULT THE NIOSH RESPIRATOR DECISION LOGIC FOUND IN
PUBLICATION NO. 87-116 OR ANSI Z88.2-1992. |
Glove Protection:
NEOPRENE OR NITRILE
RUBBER GLOVES SHOULD BE WORN. ENSURE COMPLIANCE WITH OSHA'S
PERSONAL PROTECTIVE EQUIPMENT (PPE) STANDARD FOR HAND
PROTECTION, 29 CFR 1910.138. |
Eye Protection:
CHEMICAL GOGGLES
SHOULD BE WORN. ENSURE COMPLIANCE WITH OSHA'S PERSONAL
PROTECTIVE EQUIPMENT (PPE) STANDARD FOR EYE AND FACE
PROTECTION, 29 CFR 1910.133. |
Other Protection:
WEAR PROTECTIVE
CLOTHING WHEN HANDLING. REMOVE OIL SOAKED CLOTHING AND SHOES.
WASH CLOTHING AND CLEAN SHOES BEFORE REUSE. A SAFETY SHOWER
AND AN EYEWASH STATION SHOULD BE
AVAILABLE. | |
Section X -
Storage and Handling Information
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Precautions to be Taken in Handling
and Storing:
USE WITH CAUTION
AROUND HEAT, SPARKS, PILOT LIGHTS, STATIC ELECTRICITY, AND
OPEN FLAME. |
Other Precautions:
KEEP OUT OF REACH
OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING THE PRODUCT.
FOLLOW THE LABEL
DIRECTIONS. | |
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| Those
Ingredients listed above are subject to the reporting
requirements of 313 of Title III of the Superfund Amendments
and Reauthorization Act of 1986 and 40 CFR part
372. |
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| Please call
1-800-527-9919 for additional information if you are a
California customer. This MSDS is not intended for users in
the state of California. |
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| 1. THRESHOLD
LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS
AND BIOLOGICAL EXPOSURE INDICES, ACGIH, 2004. 2. OSHA
PEL. 3. VENDOR'S MSDS. 4. REGISTRY OF TOXIC EFFECTS OF
CHEMICAL SUBSTANCES, CCINFOWeb, 2004. ALL THE COMPONENTS
OF THIS PRODUCT ARE IN COMPLIANCE WITH THE TOXIC
SUBSTANCES CONTROL ACT (TSCA) AND ARE EITHER LISTED ON
THE TSCA INVENTORY OR OTHERWISE EXEMPTED FROM LISTING.
IRR:IRRITANT, FLAM/FLAMM:FLAMMABLE, COMB:COMBUSTIBLE,
CORR:CORROSIVE, CARC:CARCINOGENIC, TOX:TOXIC, N/A:NOT
APPLICABLE, N/E:NOT ESTABLISHED, COC:CLEVELAND OPEN CUP,
PMCC:PENSKY-MARTIN CLOSED CUP, TCC:TAGLIABUE CLOSED CUP,
LEL:LOWER EXPLOSION LIMIT, UEL:UPPER EXPLOSION LIMIT,
NFPA:NATIONAL FIRE PROTECTION ASSOCIATION,
IARC:INTERNATIONAL AGENCY FOR THE RESEARCH ON CANCER,
NTP:NATIONAL TOXICOLOGY PROGRAM, OSHA:OCCUPATIONAL
SAFETY & HEALTH ADMINISTRATION, ACGIH:AMERICAN
CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS,
TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE
LIMIT, STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD,
MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC,
ASPHYX:ASPHYXIANT, PNOS:PARTICLES (INSOLUBLE) NOT
OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL:ORAL,
IHL:INHALATION, HMN:HUMAN |
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