VERSACHEM CORPORATION -- GASKET SEALANT,0051,13009 -- -
===================== Product Identification ===================== Product ID:GASKET SEALANT,0051,13009 MSDS Date:01/21/1998 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:VERSACHEM CORPORATION Address:6643 42ND TERRACE NORTH City:WEST PALM BEACH State:FL ZIP:33407 Country:US Info Phone Num:561-845-2425 Emergency Phone Num:800-424-9300 (CHEMTREC) Chemtrec Ind/Phone:(800)424-9300 CAGE:0FY40 === Contractor Identification === Company Name:VERSACHEM CORPORATION Address:6643 42ND TERRACE NORTH Box:City:WEST PALM BEACH State:FL ZIP:33407 Country:US Phone:561-845-2425 CAGE:0FY40 ============= Composition/Information on Ingredients ============= Ingred Name:SILCIA, CRYSTALLINE-QUARTZ; (CRYSTALLINE SILICA) CAS:14808-60-7 RTECS #:VV7330000 < Wt:1. Other REC Limits:0.1 MG/M3 (CANADA) OSHA PEL:see Table Z-3 OSHA STEL:N/K ACGIH TLV:0.1 MG/M3 ACGIH STEL:N/K Ingred Name:ISOPROPANOL CAS:67-63-0 RTECS #:NT8050000 Minumum % Wt:10. Maxumum % Wt:30. Other REC Limits:400 PPM (CANADA) OSHA PEL:980 MG/M3;400 PPM OSHA STEL:N/K ACGIH TLV:983 MG/M3;400 PPM ACGIH STEL:1230 MG/M3;500 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA AVAILABLE. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN: MILDLY IRRITATING TO THE SKIN. EYES: EYE IRRITANT. CORNEAL DAMAGE MAY OCCUR. INHALATION: MAY CAUSE MILD IRRITATION TO THE NOSE, THROAT AND RESPIRATORY TRACT AND MAY RESULT IN CENTRAL NERV OUS SYSTEM DEPRESSION. INGESTION: IRRITATING TO THE GASTROINTESTINAL TRACT, CAUSING ABDOMINAL PAIN AND VOMITING, SOMETIMES BLOODY. INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION, LOW BLOOD PRES SURE, RAPID HEART BEAT AND LIVER DAMAGE. CHRONIC: NO ADVERSE EFFECTS ANTICIPATED FROM AVAILABLE INFORMATION. SEE TOXICOLOGICAL SECTION FOR TOXICOLOGY STUDY DATA. Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONOGRAPHS, VOLUME 68, 1997: GROUP 1. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN. HUMAN: LUNG. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:EXISTING EYE, SKIN AND RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH CLEAN WATER FOR AT LEAST 15 MINUTES WHILE GENTLY HOLDING EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN: IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND EXCESS CONTAMINANT. FLUSH SK IN WITH WATER. WASH THOROUGHLY WITH SOAP AND WARM WATER. CONSULT A PHYSICIAN IF IRRITATION DEVELOPS. INHALATION: REMOVE PATIENT TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL A TTENTION IF SYMPTOMS PERSIST. INGESTION: GIVE TWO GLASSES OF WATER IF PATIENT IS NOT UNCONSCIOUS OR DROWSY; INDUCE VOMITING BY GIVING 2 TABLESPOONS SYRUP OF IPECAC. KEEP VICTIM'S HEAD BELOW HIPS WHILE VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:=11.7C, 53.F ESTIMATE Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . CLEAR AREA OF UNPROTECTED PERSONNEL. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR. COOL FIRE-EXPOSED CONTAINERS WITH WATER S PRAY. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID CLASS IB. CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES COULD RUPTURE FROM VAPOR PRESSURE BUILDUP. HAZARDOUS PRODUCTS OF COMBUSTION: CARBON MONOXIDE, CARBON DIOXIDE AND OTHER UNKNOWN ORGANIC COMPOUNDS. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID PERS CONT. ELIM IGNIT SOURCES. VENT AREA. DIKE, CONTAIN & ABSORB W/CLAY, SAND/OTHER SUITABLE MATL. WEAR APPROP NIOSH APPRVD RESP & PROT CLTHG. FOR LGE SPILLS, PUMP TO STOR/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH AS CLAY, SAND/OTHER SUITABLE MATL & DISPOSE OF PROPERLY. FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE. SML SPILLS: TAKE UP W/ABSORB MATL & PLACE IN APPROP CONTRS FOR (SUP DAT) ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPOR OR MIST. DO NOT GET IN EYES, ON SKIN OR CLOTHING. CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINER WHEN POURING. KEEP AWAY FROM HEAT, FLAME OR SPARKS. USE NON-SPARKING TOOLS. KEEP IN A COOL PLACE, WITHOUT DIRECT EXPOSURE TO SUNLIGHT. Other Precautions:KEEP CONTR TIGHTLY CLOSED & OTHERWISE IN ACCORDANCE W/NFPA REGS. MAINTAIN AIR SPARCE IN STOR CONTRS. PROVIDE APPROP VENT/NIOSH APPRVD RESP PROT AGAINST DECOMP PRODS DURING WELDING/FLAME CUTTING OPERAT IONS & TO PROTECT AGAINST SILICA DUST DURING SANDING/GRINDING OF CURED PROD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IF AIR CONCENTRATIONS ARE BELOW PERMISSIBLE LEVELS. OTHERWISE, A NIOSH APPROVED AIR PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE MAY BE PERMISSIBLE. USE A NIOSH APPROVED POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, OR UNKNOWN EXPOSURE LEVELS. Ventilation:USE VENTILATION THAT IS ADEQUATE TO KEEP EMPLOYEE EXPOSURE TO AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS. Protective Gloves:WEAR IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . WEAR IMPERVIOUS BUTYL RUBBER CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED. OBSERVE LABEL PRECAUTIONS. Supplemental Safety and Health SPILL PROC: DISP. PVNT SPILL FROM ENTERING DRAINAGE/SEWER SYS, WATERWAYS, & SURF WATERS. USE BONDING/GROUNDING LINES & NON-SPKG TOOLS. PHYSICAL/CHEM PROPERTIES: VOC (GRAMS/LITER): N/K; PERCENT SOLIDS BY WT: >60; PH (5% SOLN/SLURRY IN WATER): N/K. ================== Physical/Chemical Properties ================== Boiling Pt:=82.2C, 180.F Melt/Freeze Pt:=-88.3C, -127.F Vapor Pres:32 MMHG @ 68F Vapor Density:2.1(AIR=1) Spec Gravity:0.8 - 1.5 pH:SEE SUP DAT Evaporation Rate & Reference:1.4 (BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:LIQUID, WITH SOLVENT ODOR. Percent Volatiles by Volume:<40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT USE UNCURED MATERIAL WITH ALUMINUM EQUIPMENT AT TEMPERATURES ABOVE 120F. AVOID CONTACT WITH STRONG OXIDIZING AGENTS, ACIDS, CHLORINE, ACETALDEHYDE, ETHYLENE OXIDE. Stability Condition to Avoid:AVOID HEAT, OPEN FLAMES, TEMPERATURES ABOVE 120F AND IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND UNKNOWN PRODUCTS OF DECOMPOSITION. =================== Toxicological Information =================== Toxicological Information:ACUTE ORAL LD50 (RAT)/ACUTE DERMAL LD50 (RABBIT)/ACUTE INHAL LC50 (RAT)/EYE IRRIT: NO DATA AVAIL. SUBCHRONIC EFTS: RAT & MOUSE INHAL TOXICITY: SUBCHRONIC NOAEL WAS 500 PPM BASED ON CLINICAL SIGNS OF C NS DEPRESS (BOTH SPECIES) & INCRD BODYWT & BLOOD EFTS (RAT ONLY) SEEN AT 1500 PPM. CARCIN, TERATOGENICITY, & MUTAGENICITY: IN RESPONSE TO TSCA TEST RULE, SEVERAL STUDIES OF IPA HAVE NOW BEEN COMPLETED . STUDIES & THEIR RSLTS ARE AS FOLLOWS: 1) BOTH MUTAGENICITY STUDIES, MOUSE MICRONUCLEUS & CHO ASSAYS, WERE NEG. 2) RAT & RABBIT ORAL TERATOGENICITY & DEVEL TOXICOLOGY: A) THERE WAS NO EVIDENCE THAT I PA CAUSED TERATOGENICITY (OTHER INFO) ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NO DATA AVAILABLE. MOBILITY AND PERSISTENCE: NO DATA AVAILABLE. ENVIRONMENTAL FATE: NO DATA AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF THIS PRODUCT BECOMES A WASTE, IT WOULD BE A HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). DISPOSE OF ACCORDING TO APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:PROPER SHIPPING NAME: ISOPROPANOL SOLUTION. HAZARD CLASS: 3. UN NUMBER: 1219. PACKING GROUP: II. EMERGENCY RESPONSE GUIDE NUMBER: 129. IMDG PAGE NUMBER: 3244. ===================== Regulatory Information ===================== SARA Title III Information:FOR PURPOSES OF SARA SECTION 312 HAZ MATLS INVENTORY REPORTING, THE FOLLOWING HAZ CLASSES APPLY TO THIS MATL: IMMED HLTH HAZ - DELAYED HLTH HAZ - FIRE HAZ. ACCORDING TO APPROP REGS FOR EMER PLANNING & RELEASE REPORTING REQS FOR SUBSTANCES ON SARA SECTION 301 EXTREMELY HAZ SUBSTANCE LIST, NO INGS IN THIS MATL ARE CONSIDERED EXTREMELY HAZ. NO INGS IN THIS MATL ARE LISTED IN SARA SECTION 313 LIST OF TOX CHEMS, FOR WHICH RELEASE REPORTING MAY BE REQUIRED. FOR SPECIFIC REQS, CONSULT APPROP REGS. Federal Regulatory Information:U.S. FED REGS: TSCA: ALL INGS OF THIS PROD ARE LISTED/ARE EXEMPT FROM LISTING, ON TSCA INVENTORY. EXPORT NOTIFICATION IS REQUIRED UNDER TSCA SECTION 12B. THE FOLLOWING RCRA CODE(S) APPLIES TO THIS MAT L IF IT BECOMES WASTE: D001. REGULATORY STATUS OF HAZ CHEM CONSTITUENTS OF THIS PROD: CERCLA RQ (LBS): NONE; TSCA 12B EXPORT NOTIFICATION: CRYSTALLINE SILICA: NOT REQUIRED; ISOPROPANOL: REQUIRED. CANA DIAN REGS: WHMIS HAZ CLASS(ES): B3; D2B. ALL COMPONENTS OF THIS PROD ARE ON THE DOMESTIC SUBSTANCES LIST. State Regulatory Information:OTHER INFO: OFFSPRING (MAX DOSE 1200 PPM). MILD, REVERSIBLE, LIVER EFFECTS HAVE BEEN NOTED WHEN LABORATORY ANIMALS HAVE BEEN OVEREXPOSED TO IPA. TOXICOLOGICAL INFORMATION ON HAZARDOUS CHEMICAL CONSTIT UENTS OF THIS PRODUCT: CRYSTALLINE SILICA: ORAL LD50 (RAT): N/K; DERMAL LD50 (RABBIT): N/K; INHALATION LC50 4HR (RAT): N/K. ISOPROPANOL: ORAL LD50 (RAT): 5045 MG/KG; DERMAL LD50 (RABBIT): 12.8 G/KG; INHALATION LC50 4HR (RAT): 22627 PPM ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.